Does librenms have the ability to add monitoring items, such as zabbix's item

Does librenms have the ability to add monitoring items, such as zabbix’s item

Do those devices have snmp?

yes,
I mean, I have special monitoring requirements, I need to add items, such as items in zabbix, templates.

I have no idea what those templates are.

No Zabbix, but you can add Nagios services. Anything specific you are looking to monitor ?